The Use of Uio-66 Metal–Organic Frameworks as a High-Performance Catalyst for the Isomerization Process of endo- to exo-Dicyclopentadiene in a Solvent-Free Condition

نویسندگان

چکیده

Exo-tetrahydrodicyclopentadiene (tricyclo[5.2.1.02,6]decane) or JP-10 is a synthetic jet fuel, which can be used as high-density fuel in the air-breathing missile engineers and supersonic combustion ramjets. It produced from fully saturated version of exo-dicyclopentadiene (exo-DCPD). This work introduces new green method for isomerization endo-dicyclopentadiene (endo-DCPD) to exo- form presence metal–organic frameworks (MOFs). The synthesized UiO-66 UiO-66-vac two suitable MOF catalysts are process solvent-free condition. design experiment optimize reaction conditions including time, temperature catalyst loading. High yield excellent conversion endo- exo-DCPD obtained by reacting with at lower levels time temperature. Solvent-free, environmentally friendly, simple process, reusable catalyst, availability materials advantages this process.

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ژورنال

عنوان ژورنال: Journal of Inorganic and Organometallic Polymers and Materials

سال: 2022

ISSN: ['1574-1451', '1574-1443']

DOI: https://doi.org/10.1007/s10904-022-02452-4